R. Oldenbourg Verlag: Zeitschrift für Kristallographie - New Crystal Structures

Volume 216 · Issue 4 · 2001
Zeitschrift für Kristallographie - New Crystal Structures
International journal for structural, physical, and chemical aspects of crystalline materials
Language of publication: English
Volume 216: 4 issues appear in 2001
ISSN: 1433-7266

Rubrik: Inorganic Crystal Structures

A.-V. Mudring and M. Jansen
Crystal structure of monocesiumaurate(I), CsAuO
NCS 409553

A.-V. Mudring and M. Jansen
Crystal structure of monorubidiumaurate(I), RbAuO
NCS 409552

A.-V. Mudring and M. Jansen
Crystal structure of tetrarubidium dichloride monooxide, Rb₄(Cl₂O)
NCS 409578

Mehtap Emirdag-Eanes and James A. Ibers
Crystal structure of dipotassium tetrathiomolybdate, K₂MoS₄
NCS 409563

Ismail Ijjaali and James A. Ibers
Crystal structure of palladium selenide, PdSe
NCS 409568

Ismail Ijjaali and James A. Ibers
Crystal structure of digadolinium orthosilicate telluride, Gd₂(SiO₄)Te
NCS 409569

Mehtap Emirdag-Eanes and James A. Ibers
Crystal structure of tricesium tetrathiovanadate(V), Cs₃VS₄, and of trirubidium tetrathiovanadate(V), Rb₃VS₄
NCS 409564 409565

Anna S. Gardberg and James A. Ibers
Crystal structure of hexapraseodymium dititanium septasulfide hexaoxide, Pr₆Ti₂S₇O₆
NCS 409558

C. Falah, H. Boughzala and T. Jouini
Crystal structure of tripotassium dibismuth phosphate, K₃Bi₂(PO₄)₃
NCS 409582

C. Zheng, Hj. Mattausch and A. Simon
Crystal structure of galotrilanthanum triiodide, La₃GaI₃
NCS 409561

C. Zheng, Hj. Mattausch and A. Simon
Refinement of the crystal structure of lanthanum digallide, LaGa₂
NCS 409562

G. Krauß and V. Krämer
Crystal structure of pentamercury dialuminum octaselenide, Hg₅Al₂Se₈
NCS 409566

G. Derrien, M. Tillard and C. Belin
Crystal structure of strontium tantalum arsenide oxide, Sr₃TaAs₃O, containing the pseudo-tetrahedral anion TaAs₃O^6–
NCS 409567

W. Carrillo-Cabrera, R. Cardoso Gil and Yu. Grin
Refinement of the crystal structure of monocalcium dialuminide digermanide, Ca[Al₂Ge₂]
NCS 409570

F. Zürcher, S. Wengert and R. Nesper
Crystal structure of barium dimagnesium dilithium disilicide, BaMg₂Li₂Si₂, and of barium dimagnesium dilithium digermanide, BaLi₂Mg₂Ge₂
NCS 409575 409576

F. Zürcher and R. Nesper
Crystal structure of hexabarium pentamagnesium trilithium dodecagermanide, Ba₆Mg_4.9Li_3.1Ge₁₂
NCS 409572

F. Zürcher and R. Nesper
Crystal structure of octacalcium dimagnesium monolithium octasilicide, Ca₈Mg_2.0Li_1.0Si₈, and of octacalcium dimagnesium monolithium octagermanide, Ca₈Mg_1.82Li_1.18Ge₈
NCS 409573 409574

J. Haberecht, H. Borrmann and R. Kniep
Refinement of the crystal structure of iron dibromide, FeBr₂
NCS 409571

Rubrik: Organic and Metalorganic Crystal Structures

H. J. Lindner, S. Foro, P. Nemes and P. Scheiber
Crystal structure of 11-methyl-7,11-diazatricyclo[7.3.1.0^2,7]tridecan-13-ols, C₁₂H₂₂N₂O, solid state conformation of syn- and trans-isomers
NCS 133810 133811

U. Turpeinen, I. Mutikainen, M. Klinga and R. Hämäläinen
Crystal structure of hexadecaammomium tetra[dimethyl(2-hydroxyethyl)ammonium] cyclo-tetrakis[sodium-m-heptamolybdato(VI)-O¢,O¢¢,O¢¢¢:O¢¢¢¢,O¢¢¢¢¢,O¢¢¢¢¢¢](5-) tetrawater, (NH₄)₁₆(C₄H₁₂NO)₄[NaMo₇O₂₄]₄ · 4H₂O
NCS 133810 1267-581

Yuri V. Mironov, Thomas E. Albrecht-Schmitt, Donna M. Smith and James A. Ibers
Crystal structure of octachlorotetra(m₃-telluro)tetradimethylformamidotetrarhenium(IV)dimethylformamide, C₁₅H₃₅Cl₈N₅O₅Re₄Te₄
NCS 1267-642

J. Kaizer, J. Pap, G. Speier, M. Réglier and M. Giorgi
Crystal structure of {(m-carbonato)bis[3,3¢-iminobis(N,N-dimethylpropyl-amine)]copper(II)} diperchlorate hydrate, [(Cu(idpa))₂(CO₃)](ClO₄)₂ · H₂O
NCS 1267-645

S. Akine, K. Sumitomo and T. Nabeshima
Crystal structure of 1⁵,8⁵,10⁵,12⁵,19⁵,21⁵,24⁵,27⁵-octa-t-butyl-10²,21²,24²,27²-tetrakis[(2-methoxy)ethoxy]-2,7,13,18-tetraoxa-4,15(5,2),5,16(2,5)-tetrapyridina-1,8,19(2,1,3),12(1,2,3),10,21,24,27(1,3)-dodecabenzenatricyclo[17.3.3.3^8,12]-octacosaphane tetrakis(dichloromethane), (C₁₂₄H₁₅₂N₄O₁₂)(CH₂Cl₂)₄
NCS 1267-646

D. Lentz, E. Nandanan and H.-U. Reißig
Crystal structure of methyl 6S*,8S*-9-butyl-8-hydroxy-8-isopropyl-5,6,7,8-tetrahydrobenzocyclooctene-6-carboxylate, C₂₁H₃₀O₃
NCS 1267-654

A. Aydin, C. Arici, T. Önkol, Y. Akkoc and M. F. Sahin
Crystal structure of 6-benzoyl-2-benzoxazolinone-3-propionitril, C₁₇H₁₂N₂O₃
NCS 1267-655

W. A. Pearce, S. M. Pyke and E. R. T. Tiekink
Crystal structure of 1-(4-nitrophenyl)-3-(phenylsulfonyl)-2,5-dihydro-1H-pyrrole, C₁₆H₁₄N₂O₄S
NCS 1267-656

A. Duthie, P. J. Scammells, A. Katsifis and E. R. T. Tiekink
Crystal structure of (4-bromonaphthalen-2-yl) acetonitrile, C₁₂H₈BrN
NCS 1267-663

L. Liu, R. N. Warrener, R. A. Russell and E. R. T. Tiekink
Crystal structure of dimethyl 4,5-dimethylene-15-oxahexa-cyclo-[6.6.1.1^3,6.1^10,13.0^2,7.0^9,14]heptane heptan-1,8-dicarboxylate, C₂₂H₂₆O₅
NCS 1267-664

S. Wang, R. N. Warrener, R. A. Russell and E. R. T. Tiekink
Crystal structure of (1a,2b,3a,4b,5a,12a,13b,14a,15b,16a,17b,18a,25a,26b)-N-(2-methoxyethyl)-5,12,18,25-tetraphenyl-27,28,29,30-tetraoxadeca-cyclo-[14.10.1.1^3,14.1^5,12.1^18,25.0^2,15.0^4,13.0^6,11.0^17,26.0^19,24]triaconta-6,8,10,19,21,23-exaen-2,15-carboximide—chloroform (1/2), C₅₅H₄₃NO₇· 2CHCl₃
NCS 1267-674

A. J. Liepa, R. H. Nearn and E. R. T. Tiekink
Crystal structure of 2-[5-(2-chlorophenyl)tetrazol-1-yloxy]-1-piperidin-1-yl-ethanone, C₁₄H₁₆ClN₅O₂
NCS 1267-673

M. Jevric, D. K. Taylor and E. R. T. Tiekink
Crystal structure of 2-(2-hydroxy-1-naphthyl)-1-phenyl-1-ethanone, C₁₈H₁₄O₂
NCS 1267-667

M. Jevric, D. K. Taylor and E. R. T. Tiekink
Crystal structure of 2-(1-methylnaphtho[2,1-b]furan-2-yl)acetic acid, C₁₅H₁₂O₃
NCS 1267-668

M. Jevric, D. K. Taylor and E. R. T. Tiekink
Crystal structure of 1-[(E)-2-[4-(trifluoromethyl)phenyl]-1-ethenyl]-naphthalene, C₁₉H₁₃F₃
NCS 1267-671

M. C. Kimber, S. F. Lincoln, A. D. Ward and E. R. T. Tiekink
Crystal structure of 4-methyl-N-(2-methoxy-5-acridinyl)benzene sulfonamide, C₂₁H₁₈N₂O₃S
NCS 1267-672

P. Razzino, A. D. Ward and E. R. T. Tiekink
Refinement of the crystal structure of 2-hydroxyimino-2-phenylacetonitrile, C₈H₆N₂O, at 173 K
NCS 1267-669

A. D. Ward, V. R. Ward and E. R. T. Tiekink
Crystal structure of 5-methyl-1,4-di[2-(phenylselanyl)cyclohexyl]-4H-1,2,3,4-tetraazol-1-ium perchlorate, [(C₆H₅SeC₆H₁₀)₂CH₃CN₄]ClO₄
NCS 1267-661

A. D. Ward, V. R. Ward and E. R. T. Tiekink
Crystal structure of 1-(vinylselenonyl)benzene, C₆H₅SeO₂CH=CH₂
NCS 1267-666

A. D. Ward, V. R. Ward and E. R. T. Tiekink
Crystal structure of N1-[2-(phenylseleninyl)cyclohexyl]benzamide, C₁₉H₂₁NO₂Se
NCS 1267-662

P. J. Kerr, S. M. Pyke, A. D. Ward and E. R. T. Tiekink
Crystal structure of (Z)-3-(1,3-benzodioxol-5-yl)-3-chloro-1-[2,4-di(benzyloxy)-6-hydroxyphenyl]-2-propen-1-one, C₃₀H₂₃ClO₆
NCS 1267-680

A. D. Ward, V. R. Ward and E. R. T. Tiekink
Crystal structure of anti-4-bromobenzaldehyde oxime, C₇H₆BrNO
NCS 1267-675

A. D. Ward, V. R. Ward and E. R. T. Tiekink
Crystal structure of syn-4-bromobenzaldehyde oxime, C₇H₆BrNO
NCS 1267-676

P. J. Kerr, S. M. Pyke, A. D. Ward and E. R. T. Tiekink
Crystal structure of 1-[2,4-di(benzyloxy)-6-hydroxyphenyl]-3-phenyl-2-propyn-1-one, C₂₉H₂₂O₄
NCS 1267-678

P. J. Kerr, S. M. Pyke, A. D. Ward and E. R. T. Tiekink
Crystal structure of (E)-1,3-di(2,4,6-trimethoxyphenyl)-2-propen-1-one, C₂₁H₂₄O₇
NCS 1267-679

K. A. Turner, W. H. F. Sasse and E. R. T. Tiekink
Crystal structure of dimethyl [2-(4¢-nitrophenyl)-3-phenyl-2H-azirin-2-yl]phosphonate, C₁₆H₁₅N₂O₅P
NCS 1267-690

G. E. Gream, P. K. Kirkbride and E. R. T. Tiekink
Crystal structure of 2RS-p-methoxyphenyl-8SR-5-phenyl-3,5,7-triazatricyclo[6.5.1.0^3,7]tetradeca-9,11,13-triene-4,6-dione, C₂₄H₂₁N₃O₃
NCS 1267-691

M. Golic, R. N. Warrener, R. A. Russell and E. R. T. Tiekink
Crystal structure of (1SR,8RS,15SR,19RS)4,6-dimethoxy-17-methyl-3,5-diazapentacyclo[6.6.5.02,7.09,14.015,19]-nonadec-2,4,6,9,11,13-hexaene-16,18-dione, C₁₉H₁₇N₃O₄, the major adduct from the Diels-Alder reaction of maleic anhydride with 2,4-dimethoxy-1,3-diazaanthracene
NCS 1267-692

E. R. T. Tiekink
Crystal structure of 2,2¢>-bipyridyl adduct of bis(dibutyldithiocarbamato)zinc(II), [Zn(S₂CNBu₂)₂(bipy)]
NCS 1267-721

A. Ries, J. Sander and K. Hegetschweiler
Crystal structure of 2,3-O-dimethyl-5,6-O-isopropylidene-L-ascorbic acid, C₁₁H₁₆O₆
NCS 1267-657

A. Ries, J. Sander and K. Hegetschweiler
Crystal structure of 2,3-O-ethandiyl-5,6-O-ditosyl-L-ascorbic acid, C₂₂H₂₂O₁₀S₂
NCS 1267-658

J. Zukerman-Schpector
Crystal structure of carbomethoxy-6-hydroxy-1,2,5,5-tetramethyl-1,2,3,5,6,7,8,8a-octahydronaphtalene, C₁₆H₂₆O₃
NCS 1267-659

J. Zukerman-Schpector, P. R. Olivato, M. L. T. Hui and A. Rodrigues
Crystal structure of 4¢-methylphenyl-2-ethylsulfonyl thioacetate, C₁₁H₁₄O₃S₂
NCS 1267-684

J. Iulek, J. Zukerman-Schpector, C. C. Stadler, A. Tozetto and M. Vega
Crystal structure of 4-aza-2-(hydroxyimino)-3-methyl-5-(2-pyridyl)pent-3-ene, C₁₀H₁₃N₃O
NCS 1267-708

C. Bruhn, Y. Arendt and D. Steinborn
Crystal structure of O¹,O²,O³,O⁶-tetraacetyl-O4-[tetra-O-acetyl-b-D-glucopyranosyl]-a-D-glucopyranose(octa-O-acetyl-a-D-cellobiose), C₂₈H₃₈O₁₉
NCS 1267-660

A. Mahjoub, H. Zantour and S. Masson
Crystal structure of 1,3,5,7-tetrabenzyl-2,4,6,8,9,10-hexathia-tricyclo[3.3.1.1^3,7]decane, C₃₂H₂₈S₆
NCS 1267-665

H. Hartl, I. Brüdgam, H.-U. Reißig and M. Buchholz
Crystal structure of (4S*,5R*,6S*)-6-ethoxy-4-[(1R*)-(1-hydroxy-1-phenyl)methyl]-3,5-diphenyl-5,6-dihydro-4H-1,2-oxazine, C₂₅H₂₅NO₃
NCS 1267-670

O. Rademacher, M. Berndt and H.-U. Reißig
Crystal structure of 4R*,4aS*,5S*-5-hydroxy-4-(1-hydroxy-1-methylethyl)-5-methyl-4,4a,5,6,7,8-hexahydronaphthalene-2-carbonitrile—water (1/1), C₁₅H₂₁NO₂ · H₂O
NCS 1267-685

M. Cetina, A. Hergold-Brundic, D. Mrvos-Sermek, Z. Dzolic and M. Mintas
Crystal structure of ethyl(1S,2R)-1-benzamido-2-[(S)-2,2-dimethyl-1,3-dioxolan-4-yl]cyclopropanecarboxylate, C₁₈H₂₃NO₅
NCS 1267-677

M.-L. Hu, Z.-M. Jin, Q. Miao and L.-P. Fang
Crystal structure of tris(acetylacetonato)iron(III), C₁₅H₂₁O₆Fe, at 20 K
NCS 161834

J. Canisius, M. Schürmann, H. Preut and N. Krause
Crystal structure of ethyl (Z)-2-(acetylamino)-6,6-dimethyl-2-hepten-4-ynoate, C₁₃H₁₉NO₃
NCS 1267-682

A. R. Mahjoub and A. Morsali
Crystal structure of meso nitrato-O,O¢-bis(1,10-phenantroline) isothiocyanatolead(II), C₂₅H₁₆N₆O₃PbS
NCS 162628

N. T. Do Valle, C. A. De Simone, M. A. Pereira, A. V. Pinto and V. R. S. Malta
Crystal structure of 2,2-dimethyl-naphto[1,2b]1,2-dihydrofuran-4,5-dione, C₁₄H₁₂O₃
NCS 1267-686

A. Morsali, A. Ramazani, F. Jamali and F. Gouranlou
Crystal structure of diaqua-bis[N-(2-pyridyl)carbonylaniline]zinc(II) diperchlorate, Zn(C₁₂H₁₆N₂O)₂(H₂O)₂(ClO₄)₂
NCS 1267-687

A. Morsali, A. Ramazani, F. Jamali and F. Gouranlou
Crystal structure of pyridine-2-carbaldehyde thiosemicarbazonium perchlorate, (C₇H₉N₄S)(ClO₄)
NCS 1267-714

S. Henkel, D. Shaw, A. Lieberknecht and V. Jäger
Crystal structure of methyl 2,3-di-O-benzyl-4,6-cyclo-4,6-dideoxy-b-D-galactopyranoside, C₂₁H₂₄O₄
NCS 1267-681

S. Henkel, D. Shaw and V. Jäger
Crystal structure of (3R,4R,5R)-5-iodomethyl-3,4-O-isopropylidenedioxy-1-phenylamino-pyrrolidine-2-one, C₁₄H₁₇IN₂O₃
NCS 1267-683

S. Henkel, D. Shaw, H.-Q. Dong and V. Jäger
Crystal structure of (1S,2R,3R,5aR,6S,7R,8R,10aR)-5,10-di-(tert-butoxycarbonyl)-3,8-di-(iodomethyl)-1,2:6,7-di-isopropylidenedioxy-perhydro-dipyrrolo[1,2-b:1,2-e]-1,2,4,5-tetrazine, C₂₆H₄₂I₂N₄O₈
NCS 1267-697

A. Spannenberg, V. V. Burlakov and U. Rosenthal
Crystal structure of [2,2-bis(h⁵-pentamethylcyclopentadienyl)-bis-(m,h¹:h²-2-trimethylsilyl-ethinyl)titanium(IV) lithium][2,2-bis(h⁵-pentamethylcyclopentadienyl)-oxotitanium(III)—tetrahydrofurane (1/0.5),
C₅₀H₇₈LiOSi₂Ti₂ · 0.5C₄H₈O
NCS 1267-689

A. Spannenberg, F. G. Kirchbauer, V. V. Burlakov and U. Rosenthal
Crystal structure of bis[(h⁵-cyclopentadienyl)(m,h¹:h²-2-trimethylsilyl-ethinyl)(chloro)titanium(III)], [CpTiCl(CCSiMe₃)]₂
NCS 1267-688

M. Ousmer, N. A. Braun, M. A. Ciufolini and M. Perrin
Crystal structure of (1S,3S,6S,7S,8S,9R)-7,9-dihydroxy-6-(4-methoxybenzyl)-3-[N-methyl-N-(4-methylphenyl)sulfonylamino]-5-azatricyclo[6.3.1.0^1.5]dodecan-4-one—water (1/1), C₂₇H₃₄N₂O₆S · H₂O
NCS 1267-695

J. C. Bryan and R. A. Sachleben
Crystal structure of 26,28-bis(2-propenyloxy)calix[4]arene, C₃₄H₃₂O₄
NCS 1267-693

M. Ranjbar, H. Aghabozorg, A. Moghimi and A. Yanovsky
Crystal structure of 2,6-diaminopyridinum bis(2,6-pyridinedicarboxylato)chromium(III) 2,6-pyridinedicarboxylic acid hemihydrate, C₂₆H₁₈CrN₆O₁₂ · 0.5H₂O
NCS 1267-696

M. S. Hussain, A. A. Isab, A. Saeed and A. R. Al-Arfaj
Crystal structure of bromotri(phenyl)phosphinesulphidegold(I), (C₆H₅)₃PSAuBr
NCS 1267-700

M. Krimi Ammar, F. Ben Amor, A. Driss and T. Jouini
Refinement of the crystal structure of di(acetatodiethanolamin)copper(II) complex, Cu[N(CH₂COO)(CH₂CH₂OH)₂]₂
NCS 1267-707

C. Bavoux, C.-H. Fabritius, B. Clique, N. Monteiro and G. Balme
Crystal structure of iodo-(9-methylene-5,6-dihydro-10,10-dimethoxycarbonyl-benzo[f]pyrrolidino[2,1-a]isoquinoline-5-methyl)-triphenylphosphine-palladium(II)—dichloromethane (1/0.5), (C₄₀H₃₇INO₄PPd) · 1/2 (CH₂Cl₂)
NCS 1267-701

K. Chkirate, R. Regragui, E. M. Essassi and M. Pierrot
Crystal structure of diaquabis[N-2-aminophenyl-5-methylpyrazol-yl acetamido]zinc(II) diperchlorate, C₂₄H₃₄N₈O₄Zn(ClO4)₂
NCS 1267-702

M. Vogt, T. Schütt, T. Kemmerich, T. M. Klapötke and W. Beck
Crystal structure of trans-azido-bis(dimethylglyoximato)-triphenylphosphine-cobalt(III), C₂₆H₂₉CoN₇O₄P, at 200 K
NCS 1267-703

B. Tinant, D. Depré and L. Ghosez
Crystal structure of (1S,5R,6R,7R)-7-(tert-butyldiphenylsilyloxy)-6-vinyl-2-oxabicyclo[3.3.0]octan-3-one, C₂₅H₃₀O₃Si
NCS 1267-704

B. Tinant, D. Depré and L. Ghosez
Crystal structure of (1S,5R,6S,7R)-7-(tert-butyldiphenylsilyloxy)-6-vinyl-2-oxabicyclo[3.3.0]octan-3-one, C₂₅H₃₀O₃Si
NCS 1267-705

B. Tinant, D. Depré and L. Ghosez
Crystal structure of (1R,5S,6S,7R)-7-(tert-butyldiphenylsilyloxy)-6-vinyl-2-oxabicyclo[3.3.0]octan-3-one, C₂₅H₃₀O₃Si
NCS 1267-706

V. Sourdon, G. Boyer and J.-P. Galy
Crystal structure of 4,9-dimethyl-9,10-dihydroacridine, C₁₅H₁₅N
NCS 1267-709

F. F. Fleming, Y. Pu, R. E. Norman and S.-C. Chang
Crystal structure of 2-[(tert-butyldimethylsilyloxy)-6-phenyl]-1-cyclohexene-1-carbonitrile, C₁₉H₂₇NOSi
NCS 1267-710

C. Meenakshi, V. Ramamoorthy, S. Muthusubramanian, S. Sivasubramanian, T. Ziegler and J. Lex
Crystal structure of 2-phenyl-2-cyclohexene-1-one oxime, C₁₂H₁₃NO
NCS 1267-711

C. Meenakshi, V. Ramamoorthy, S. Muthusubramanian, S. Sivasubramanian, T. Ziegler and J. Lex
Crystal structure of 2-(4-methoxyphenyl)-2-cyclohexene-1-one oxime, C₁₃H₁₅NO₂
NCS 1267-712

C. Meenakshi, V. Ramamoorthy, S. Muthusubramanian, S. Sivasubramanian, T. Ziegler and J. Lex
Crystal structure of 2-(3,4-dimethylphenyl)-2-cyclohexene-1-one oxime, C₁₄H₁₇NO
NCS 1267-713

A. Grünewald-Lüke, B. Marler and H. Gies
Crystal structure of clathrasil sigma-2 containing 3-azabicyclo[3.2.2]nonan as the guest molecule, ABN-sigma-2, (C₈H₁₅N)₄[Si₆₄O₁₂₈]
NCS 1267-715

G. F. de Lima, R. H. A. Santos, J. Souza Jr. and J. R. Lechat
Crystal structure of N-(1,2-diphenyl-2-hydroxyethylidene)-N¢-(2,4-dinitrophenyl)-hydrazine, C₂₀H₁₆N₄O₅
NCS 1267-716

A. Spannenberg, B. Ait Allal, L. El Firdoussi, A. Karim and M. Beller
Crystal structure of bis(p-allyldihydro-valencene)dichlorodipalladium, C₁₅H₂₅ClPd
NCS 1267-717

K. Fukui, D. Hesek, M. Oelgemöller and Y. Inoue
Crystal structure of N-cyclooctylidene-N¢-(2,4-dinitrophenyl)-hydrazine, C₁₄H₁₈N₄O₄
NCS 1267-719

E. F. Paulus, A. Burgard, H.-J. Lang and U. Gerlach
Crystal structure of (S)-(+)-6-fluoro-3,4-dihydro-2,2-dimethyl-2H-1-benzpyran-4-ammonium chloride, [(CH₃)₂(C₉OH₆)F(NH₃)]Cl
NCS 1267-720
Errata

[ New Crystal Structures ]